Distribution and Transport of Polychlorinated Biphenyls and Associated Particulates in the Hayton Millpond, South Branch Manitowoc River, 1993ñ95

Appendix 2. PCB congeners found during laboratory analysis of water and sediments in the Hayton Millpond Basin and their respective limits of detection and quantification in nanograms per liter

[From Degenhardt (1996). LOD; limit of detection, LOQ, limit of quantification; () indicates positions of chlorine substitution on biphenyl nucleus]

LOD	LOQ	Congener number and chlorine substitution position	LOD	LOQ	Congener number and chlorine substitution position
0.020	0.060	7 (2, 4)	0.035	0.11	85 (2, 2', 3, 4, 4')
.080	.27	6 (2, 3')	.030	.10	136 (2, 2', 3, 3', 6, 6')
.090	.30	5/8 (2, 3/2, 4')	.035	.11	77/110 (3, 3', 4, 4' /2, 3, 3', 4', 6)
.025	.070	19 (2, 2', 6)	.035	.11	82 (2, 2', 3, 3', 4)
.030	.090	18 (2, 2', 5)	.020	.070	151 (2, 2', 3, 5, 5', 6)
.030	.10	17 (2, 2', 4)	.025	.070	135/144 (2, 2', 3, 3', 5, 6' /2, 2', 3, 4, 5', 6)
.025	.070	24/27 (2, 3, 6/2, 3', 6)	.025	.070	149 (2, 2', 3, 4', 5', 6)
.035	.11	16/32 (2, 2', 3/2, 4', 6)	.030	.090	118 (2, 3', 4, 4', 5)
.035	.11	26 (2, 3', 5)	.030	.11	146 (2, 2', 3, 4', 5, 5')
.080	.27	28/31 (2, 4, 4' /2, 4', 5)	.030	.11	132/153 (2, 2', 3, 3', 4, 6' /2, 2', 4, 4', 5, 5')
.035	.11	33 (2', 3, 4)	.020	.070	141 (2, 2', 3, 4, 5, 5')
.055	.18	22 (2, 3, 4')	.030	.090	137/176 (2, 2', 3, 4, 4', 5/2, 2', 3, 3', 4, 6, 6')
.025	.070	45 (2, 2', 3, 6)	.035	.11	138/163 (2, 2', 3, 4, 4', 5' /2, 3, 3', 4', 5, 6)
.030	.090	46 (2, 2', 3, 6')	.040	.12	178 (2, 2', 3, 3', 5, 5', 6)
.025	.070	52 (2, 2', 5, 5)	.020	.070	182/187 (2, 2', 3, 4, 4', 5, 6' /2, 3, 4', 5, 5', 6)
.025	.070	49 (2, 2', 4, 5')	.035	.12	183 (2, 2', 3, 4, 4', 5', 6)
.035	.11	47/48 (2, 2', 4, 4' /2, 2', 4, 5)	.030	.11	185 (2, 2', 3, 4, 5, 5', 6)
.025	.070	44 (2, 2', 3, 5')	.025	.090	174 (2, 2', 3, 3', 4, 5, 6')
.035	.11	37/42 (3, 4, 4' /2, 2', 3, 4')	.030	.11	177 (2, 2', 3, 3', 4', 5, 6)
.040	.12	41/64/71 (2, 2', 3, 4/2, 3, 4', 6/2, 3', 4', 6)	.035	.11	171/202 (2, 2', 3, 3', 4, 4', 6/2, 2', 3, 3', 5, 5', 6, 6')
.030	.090	40 (2, 2', 3, 3')	.045	.14	172/197 (2, 2', 3, 3', 4, 5, 5' /2, 2', 3, 3', 4, 4'. 6, 6')
.030	.090	74 (2, 4, 4', 5)	.030	.11	180 (2, 2', 3, 4, 4', 5, 5')
.040	.12	70/76 (2, 3', 4', 5/2', 3, 4, 5)	.020	.070	199 (2, 2', 3, 3', 4, 5, 6, 6')
.050	.16	66/95 (2, 3, 4, 4'/2, 2', 3, 5', 6)	.080	.27	170/190 (2, 2', 3, 3', 4, 4', 5/2, 3, 3', 4, 4', 5, 6)
.030	.090	91 (2, 2', 3', 4', 6)	.040	.14	201 (2, 2', 3, 3', 4, 5, 5', 6)
.050	.16	56/60 (2, 3, 3', 4' /2, 3, 4, 4')	.080	.27	196/203 (2, 2', 3, 3', 4, 4', 5, 6' /2, 2', 3, 4, 4', 5, 5', 6)
.050	.16	84/92 (2, 2', 3, 3', 6/2, 2', 3, 5, 5')	.080	.27	195/208 (2, 2', 3, 3', 4, 4', 5, 6/2, 2', 3, 3', 4, 5, 5', 6, 6')
.025	.070	101 (2, 2', 4, 5, 5')	.030	.11	194 (2, 2', 3, 3', 4, 4', 5, 5')
.025	.070	99 (2, 2', 4, 4', 5)	.040	.14	206 (2, 2', 3, 3', 4, 4', 5, 5', 6)
.030	.090	97 (2, 2', 3', 4, 5)	.035	.11	128 (2, 2', 3, 3', 4, 4')
.035	.11	87 (2, 2', 3, 4, 5')	.080	.27	167 (2, 3', 4, 4', 5, 5')

Return to WRIR-99-4101

Appendix 2. PCB congeners found during laboratory analysis of water and sediments in the Hayton Millpond Basin and their respective limits of detection and quantification in nanograms per liter

7 (2, 4)

85 (2, 2', 3, 4, 4')

6 (2, 3')

136 (2, 2', 3, 3', 6, 6')

5/8 (2, 3/2, 4')

77/110 (3, 3', 4, 4' /2, 3, 3', 4', 6)

19 (2, 2', 6)

82 (2, 2', 3, 3', 4)

18 (2, 2', 5)

151 (2, 2', 3, 5, 5', 6)

17 (2, 2', 4)

135/144 (2, 2', 3, 3', 5, 6' /2, 2', 3, 4, 5', 6)

24/27 (2, 3, 6/2, 3', 6)

149 (2, 2', 3, 4', 5', 6)

16/32 (2, 2', 3/2, 4', 6)

118 (2, 3', 4, 4', 5)

26 (2, 3', 5)

146 (2, 2', 3, 4', 5, 5')

28/31 (2, 4, 4' /2, 4', 5)

132/153 (2, 2', 3, 3', 4, 6' /2, 2', 4, 4', 5, 5')

33 (2', 3, 4)

141 (2, 2', 3, 4, 5, 5')

22 (2, 3, 4')

137/176 (2, 2', 3, 4, 4', 5/2, 2', 3, 3', 4, 6, 6')

45 (2, 2', 3, 6)

138/163 (2, 2', 3, 4, 4', 5' /2, 3, 3', 4', 5, 6)

46 (2, 2', 3, 6')

178 (2, 2', 3, 3', 5, 5', 6)

52 (2, 2', 5, 5)

182/187 (2, 2', 3, 4, 4', 5, 6' /2, 3, 4', 5, 5', 6)

49 (2, 2', 4, 5')

183 (2, 2', 3, 4, 4', 5', 6)

47/48 (2, 2', 4, 4' /2, 2', 4, 5)

185 (2, 2', 3, 4, 5, 5', 6)

44 (2, 2', 3, 5')

174 (2, 2', 3, 3', 4, 5, 6')

37/42 (3, 4, 4' /2, 2', 3, 4')

177 (2, 2', 3, 3', 4', 5, 6)

41/64/71 (2, 2', 3, 4/2, 3, 4', 6/2, 3', 4', 6)

171/202 (2, 2', 3, 3', 4, 4', 6/2, 2', 3, 3', 5, 5', 6, 6')

40 (2, 2', 3, 3')

172/197 (2, 2', 3, 3', 4, 5, 5' /2, 2', 3, 3', 4, 4'. 6, 6')

74 (2, 4, 4', 5)

180 (2, 2', 3, 4, 4', 5, 5')

70/76 (2, 3', 4', 5/2', 3, 4, 5)

199 (2, 2', 3, 3', 4, 5, 6, 6')

66/95 (2, 3, 4, 4'/2, 2', 3, 5', 6)

170/190 (2, 2', 3, 3', 4, 4', 5/2, 3, 3', 4, 4', 5, 6)

91 (2, 2', 3', 4', 6)

201 (2, 2', 3, 3', 4, 5, 5', 6)

56/60 (2, 3, 3', 4' /2, 3, 4, 4')

196/203 (2, 2', 3, 3', 4, 4', 5, 6' /2, 2', 3, 4, 4', 5, 5', 6)

84/92 (2, 2', 3, 3', 6/2, 2', 3, 5, 5')

195/208 (2, 2', 3, 3', 4, 4', 5, 6/2, 2', 3, 3', 4, 5, 5', 6, 6')

101 (2, 2', 4, 5, 5')

194 (2, 2', 3, 3', 4, 4', 5, 5')

99 (2, 2', 4, 4', 5)

206 (2, 2', 3, 3', 4, 4', 5, 5', 6)

97 (2, 2', 3', 4, 5)

128 (2, 2', 3, 3', 4, 4')

87 (2, 2', 3, 4, 5')

167 (2, 3', 4, 4', 5, 5')