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U.S. Department of the Interior U.S. Geological Survey
USGS  Water-Resources Investigations Report 00-4245 December 2000
   

Abstract

Introduction

Description

Sampling methods

Suspended-solids transport during dredging

PCB concentration changes during dredging

PCB loading in the Fox River due to the dredging operation

PCB transport back into the river from the onshore-processing operation

Postdredging PCB concentration and loads

Adjusting water-column PCB concentrations to allow comparison with onshore-sample PCB data

Lessons learned

References

Acknowledgments and Information

 

A Mass-Balance Approach for Assessing PCB Movement During Remediation of a PCB-Contaminated Deposit on the Fox River, Wisconsin

PCB transport back into the river from the onshore-processing operation

After filter presses removed most solids from the incoming slurry, the effluent was passed through sand and carbon filters before being discharged back to the river at a rate of more than 700,000 gal/d. On five days, 80-L samples were collected by the USGS (over an 8­12 hour period) from the shore-process-discharge pipe. Total PCB concentrations in the effluent ranged from 82 ­676 ng/L with a mean concentration of 422 ng/L. These values did not appear to be normally distributed. A conservative approach, applying the median concentration (509 ng/L) to the effluent volume discharged during the entire dredging operation (76,213,900 gallons), resulted in 0.147 kg of PCBs being returned to the river.Mean dissolved and particulate effluent

Of the 654 kg of PCBs that were processed onshore or held in the settling basins (Montgomery Watson, 2000; Richard Weber, Montgomery Watson, written comm., 2000), less than 0.03 percent was returned to the river. Additionally, the congener distribution (fig. 13) of these effluent samples was markedly different from that in the water column samples-most of the more chlorinated congeners (higher health risk) had been removed. Thus, a very small PCB mass was returned to the river, and this small mass was made up of a less toxic PCB mixture.


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